: Antimony trioxide . The toxicity of antimony trioxide is topical because it is a likely byproduct of the combustion of some materials "fireproofed" with antimony compounds. The primary hazard is the threat to the environment. 47 0 obj <>stream are not met since there is an absence of consistent identifiable toxic effects other than the non-specific PSP overload, which is an adaptive response not triggering a STOT classification. OSHA, IARC, and NTP do not classify antimony trioxide as a carcinogen. Chronic poisoning by antimony trioxide is also rare. Occupational exposure may cause respiratory irritation, pneumoconiosis, antimony spots on the skin and gastrointestinal symptoms. 0000008472 00000 n 1309-64-4 - GHPGOEFPKIHBNM-UHFFFAOYSA-N - Antimony trioxide - Similar structures search, synonyms, formulas, resource links, and other chemical information. 0000012811 00000 n Poisoning caused by ingestion of antimony. Sudden infant death syndrome (SIDS) has also been found to be associated with antimony poisoning. In long-term animal experiments, rats exposed to antimony trioxide via inhalation showed a high frequency of lung tumours. A silt-loam soil (pH 7.0, background 0.005 mmol Sb kg−1) was amended with Sb2O3at various concentrations. More than 70% of Sb in soil solution was present as Sb(V) (antimonate) within 2 days. Gastrointestinal toxicity Ingestion of a substantial quantity of antimony trioxide may result in nausea, vomiting and diarrhoea. Chronic exposure can lead to; antimony pneumonia, alterations in lung function, chronic bronchitis, chronic emphysema, inactive tuberculosis, pleural adhesions, and irritation. Inhalation of antimony trioxide (and similar poorly soluble Sb(III) dust particles such as antimony dust) is considered harmful and suspected of causing cancer. Subchronic and chronic inhalation studies with rats and mice have demonstrated increased incidence of lung neoplasia following antimony trioxide exposure. 0000001502 00000 n The metal and its compounds can be toxic. Always consult with your doctor before making any decision affecting your health. 0000003918 00000 n d_AO� (!�R�6Ni��r�r=���;Ћ��v:����EJ"���aJĢY���c3��0��S2� �� D1�!�W�K��������Bƒ72A�P�P����E�G�ء��z�R+鱔Ţ1#���d�I�--�V}�L`�ʾ��b�7�Y��;:��T��AOZw������'���*�;�z���� �J8ʨ�m�]�'���v{�a��"�UQCq_�vph��)kX�e�۔k����)%Jb'�u�Ⱥ�_iGm��v(dL�{�Q*k�#q+ C��ި�m���@�kX��)����� 0000002545 00000 n Elemental antimony metal does not affect human and environmental health. Magnesium or selenium deficiency increase antimony absorption and retention in the body. Despite the fact that large doses work as an emetic, if left untreated, a person may die. @ZؖdK@-�~�v�Z�J{XQ���=>��c�_^3x��^$$IP��)a *R$ᰪ��i�`�x���;ך}�1J(�9.�bj@\�-�G����|=z>��F��$��T�m�~�BȈ��0S!��I��OM�W���o��I"����!�@��/p�$���.0���?� The oxides of arsenic, antimony, and bismuth are comparable in their toxicity, but their volatilities differ widely. Antimony is usually mixed with other metals such as lead and zinc to form mixtures of metals called alloys. * Exposure to Antimony Trioxidecan irritate the nose, mouth, throat and lungs causing cough, wheezing and/or shortness of breath. Exposure to antimony trioxide may increase the risk of cancer. 0000007824 00000 n 0000001321 00000 n Antimony trioxide is considered possibly carcinogenic to humans (Group 2B) by the IARC [150] and was recently listed as reasonably anticipated to be a human carcinogen by the NTP [151]. Antimony trioxide has suspected carcinogenic potential for humans. Acute (short-term) exposure to antimony by inhalation in humans results in effects on the skin and eyes. Antimony trioxide (Sb2O3) is a widely used chemical that can be emitted to soil. 0000001060 00000 n Toxicity can also result from repeated exposure to antimony in medications, such as tartar emetic (antimony and potassium tartrate), used to induce vomiting and in treatment of helminthic and fungal infestations. The industrial use of antimony has not appeared to be … Antimony trioxide is a high-production-volume, inorganic chemical that is produced from the metalloid element antimony. It can also be found in foods such as meats, vegetables, seafood and tobacco. 0000000016 00000 n No other human health hazards were identified for antimony(III) oxide, and no risks to human health and the environment were identified from the production and use of antimony trioxide in daily life. High blood pressure, muscle break down, heart pain, Stomach and intestinal disorders (Fatigue, Gingivitis, Stomatitis), World Health Organization (WHO): 20 micrograms per liter (ug/L), S. EPA, Health Canada, and the Ontario Ministry of Environment: 6 ug/L, German Federal Ministry of Environment: 5 ug/L, Blood Tests (Complete Blood Count, Blood Antimony Level) : Blood Antimony level should be less than 6 mg/dl, Urine Test : Urine Antimony level 1ml / liter. Zd> Identification Product Name Antimony(III) oxide Cat No. 0000006747 00000 n A second group of people at risk for antimony exposure is patients suffering from schistosomiasis and leishmaniasis. 0000010019 00000 n Most commonly, the metal is used as a flame retardant in products as diverse as toys, car seat covers, engine covers for light aircraft, clothing for kids, and uniforms for fire fighters. Antimony is used as a part of the therapy for these conditions and can sometimes have toxic side effects that lead to pancreatitis and cardio toxicity. : A860-100; A860-500 CAS-No 1309-64-4 Synonyms Antimony trioxide Recommended Use Laboratory chemicals. Sections I (Health … It has also been listed as a possible human carcinogen by the International Agency for Research on Cancer. Antimony toxicity occurs either due to occupational exposure or during therapy. The guidelines for maximum permissible levels of antimony in drinking water are as follows: Remove the individual from the toxic environment. 0000004671 00000 n Those who are exposed to low doses for over long periods of time, will also show the symptoms of poisoning as mentioned above. 0000000796 00000 n 0. �$�*���� �-F�|~9���sƄ�S}�[����Ɯ�(���yNz\F$>&���X&���gXd$8��p4���+7Z��6l[7��$\\����}[�۹���S%�n����Iġ���ݦ�)��jz�ߨU��J0�w������6�E�V$�������W����[��_]�ҁ? Over fifty people were "very sick" and treated in hospital after drinking lemonade contaminated with 13 mg/L antimony. 0000001994 00000 n 0000003037 00000 n %PDF-1.4 %���� 23 0 obj <> endobj Antimony trioxide is on the Proposition 65 list because it can cause cancer. July 5, 2018 Antimony trioxide is a white crystalline solid. We hope you find the information helpful in your journey to healing! Introduction. Disclaimer: We are not medical doctors. 0000009329 00000 n IRIS assessment development process. A silt-loam soil (pH 7.0, background 0.005 mmol Sb kg−1) was amended with Sb2O3 at various concentrations. Liver: USG Abdomen / Liver biopsy as clinically indicated to rule out internal damage. endstream endobj 24 0 obj <> endobj 25 0 obj <> endobj 26 0 obj <>/ColorSpace<>/Font<>/ProcSet[/PDF/Text/ImageC/ImageI]/ExtGState<>>> endobj 27 0 obj <> endobj 28 0 obj <> endobj 29 0 obj [/ICCBased 44 0 R] endobj 30 0 obj [/Indexed 29 0 R 15 45 0 R] endobj 31 0 obj <> endobj 32 0 obj <> endobj 33 0 obj <> endobj 34 0 obj <>stream Antimony is used as a part of the therapy for these conditions and can sometimes have toxic side effects that lead to pancreatitis and cardiotoxicity. 0000006312 00000 n It is insoluble in water. %%EOF The effects of antimony and its compounds on human and environmental health differ widely. SAFETY DATA SHEET Creation Date 22-Dec-2009 Revision Date 18-Jan-2018 Revision Number 5 1. startxref Hazard Summary. Eye and eye lid inflammation (Conjuctivitis, , Keratitis). Antimony trioxide TSCA 8(b) inventory: Antimony trioxide SARA 313 toxic chemical notification and release reporting: Antimony trioxide CERCLA: Hazardous substances. 1, 1A, or 1B. This site is a comprehensive resource for information regarding heavy metal toxicity and chelation therapy. Antimony trioxide has suspected carcinogenic potential for humans. The fate and toxicity of this poorly soluble compound in soil is insufficiently known. Copyright © 2021 | WordPress Theme by MH Themes, Protocol for IV and Oral EDTA Chelation â Medical Review, FDA Public Health Advisory: Edetate Disodium, Antimony accumulates in adrenals, thyroid, kidney, liver, spleen, and bone, Binds to the good sulfhydryl detoxification chemicals groups. Low doses cause headaches, nausea, dizziness and depression. (IARC) (1989) concluded that antimony trioxide is possibly carcinogenic to humans (Group 2B), based on sufficient evidence in animals and inadequate evidence in humans. Antimony(III) oxide has suspected carcinogenic potential for humans. 0000005517 00000 n Antimony trioxide (Sb2O3) is a widely used chemical that can be emitted to soil. Antimony Review Pulmonary Toxicity Cancer Genotoxicity Mechanism ABSTRACT Although occupational exposure to antimony and its compounds can produce pulmonary toxicity, human car-cinogenic impacts have not been observed. The information is not presented with the intention to treat or diagnose any disease or condition. Adequate magnesium, selenium, and methionine decrease the absorption and retention of antimony. * Prolonged or repeated contact can cause ulcers or sores in the nose. Inhalation studies with respirable antimony trioxide … Antimony is a silvery-white metal that is found in the earth's crust. The major toxic side-effects of antimonials as a result of therapy are cardiotoxicity (~9% of patients) and pancreatitis, which is seen commonly in HIV and visceral leishmaniasis co-infections. Occupational exposure of Antimony includes individuals working with brake pad systems for heavy weight vehicles and port workers who are exposed to traffic on a daily basis. These alloys are used in lead storage batteries, solder, sheet and pipe metal, bearings, castings, type metal, ammunition, and pewter. The main signs are irritation of the respiratory tract and of the skin and a characteristic pneumoconiosis, which is visible on chest X-rays. xref Subsequently, an inhalation oncogenicity study was conducted at exposure levels of … In addition antimony trioxide is possibly carcinogenic to humans. However, these effects are only observed with female rats and after long-term exposure to high dust concentrations. Breathing air contaminated with antimony can cause eye and lung irritation, heart and lung damage, stomach pains, diarrhea, vomiting, and stomach ulcers. Carcinogenicity ACGIH classifies antimony trioxide as TLV-A2 suspected human carcinogen. Everyone is exposed to low levels of antimony in the environment. Antimony Toxicity ACGIH (2006) classified “antimony trioxide production” as a suspected human carcinogen (Group A2), although “antimony and compounds” was not similarly classified. Skin sensitising (Ss) – Recognised skin sensitiser: comes from a harmonised C&L classifying the substance as Skin Sens. Occupational exposure may cause respiratory irritation, pneumoconiosis, antimony spots on the skin and gastrointestinal symptoms. In addition antimony trioxide is possibly carcinogenic to humans. The toxicity of antimony trioxide is topical because it is a likely byproduct of the combustion of some materials "fireproofed" with antimony compounds. It is brought into this country from other countries for processing. 0 Broad agreement: comes from industry data where a majority of data submitters agree the substance is a skin sensitiser. x�b```�\V�� ��ea��������8��"PԌ�����Ɩ g �L,� k�x��R��\P�Ł�����5 j� �n )��Ȟ�ŀX�D���Q�Ƀ�C���!��C�X�цx���f!�S<7D*�)p��5XB��H3�-�8F� ���@� � "� Improvements in working conditions have remarkably decreased the incidence of antimony toxicity in the workplace. H��T]o�0}ϯ��I������-�2��QWk7�! 0000001141 00000 n Antimony is a silvery grey metalloid. The effects are hypothesized to be attributed to inhalation of poorly solubl… [ … Uses advised against Not for food, drug, pesticide or biocidal product use Details of the supplier of the safety data sheet Antimony spots (from vapor) Scaly Skin, Chickenpox, Blisters; Diarrhea, Vomiting, Digestive Upset; Hypovolemic Shock; Eye and eye lid inflammation (Conjuctivitis, , Keratitis) Chronic exposure can lead to; antimony pneumonia, alterations in lung function, chronic bronchitis, chronic emphysema, inactive tuberculosis, pleural … H��TMs�0��W�:FA3M;��N�[�dC� �����$ۉ'�dzAB���{oi�-.�&�z!Oe)4W��iM�`"Msh7��8wf|���q�t��q���+V����W�Յ�xh�'�U���5̽?���_�8au���r$. Antimony ores are mined and then mixed with other metals to form antimony alloys or combined with oxygen to form antimony oxide. Antimony trioxide is used in the production of polyethylene terephthalate (PET) water bottles. Additionally, such individuals also suffer from hair loss and develop a scaly skin rash that called lichen planus. Its TLV is 0.5 mg/m , as for most antimony compounds. Fischer 344 rats were exposed by inhalation to Sb2O3 (antimony trioxide) dust at exposure levels of 0, 0.25, 1.08, 4.92, and 23.46 mg/m3 for 6 hr/day, 5 days/week for 13 weeks followed by a 27-week observation period. It accounts for 80% of total antimony in the USA used in the manufacturing of various consumer products.1 Human exposure to antimony trioxide occurs through ambient air, consumer products and workplace settings.1 2 In consumer products, it is commonly … 0000002501 00000 n If the problem has been caused through the inhalation, ensure that the individual has fresh air to breathe.Â. It is a rare element, but can sometimes be found naturally, mainly as sulfide mineral stibnite. TRADEASIA INTERNATIONAL PTE LTD 133 Cecil Street # 12-03 Keck Seng Tower, Singapore 069535, It is insoluble in water. Antimony trioxide is classified as a carcinogen in the state of California. Another risk group for antimony exposure are patients suffering from schistosomiasis and leishmaniasis. Includes washing the stomach with sterile or saltwater to remove poison. endstream endobj 35 0 obj <>stream Antimony trioxide is both a systemic poison and a skin disease hazard, although its toxicity is three times less than that of the metal. <]>> Chelation 0000002788 00000 n 0000003114 00000 n 0000007003 00000 n * Antimony Trioxidecan cause headaches, poor appetite, nausea, vomiting, dry throat, and loss of sleep. Large doses cause vomiting, diarrhea, abdominal discomfort and tingling of the extremities. Antimony toxicity occurs either due to occupational exposure or during therapy. However, the effects will vary depending upon the amount and period of exposure. Antimony trioxide is known to pass into breast milk and to transverse the placenta only in very small amounts. ; Proposition 65 requires businesses to determine if they must provide a warning about significant exposure to listed chemicals. More information about reproductive toxicity here. Antimony trioxide is a white crystalline solid. Chelation therapy with BAL, DMSA, or DMPS has been shown to improve antimony toxicity. One compoundâantimony trioxideâis even believed to be carcinogenic, and antimony poisoning has also been known to lead to Adams-Stokes syndrome. Little antimony is currently mined in the United States. In accordance with the diantimony trioxide CSR, the NOAEL of 1686 mg/kg bw/d from a subchronic oral toxicity study in rats is selected as being the most relevant for estimating systemic effects that might be associated with dermal uptake of antimony metal or antimony (III) compounds. Symptoms of Excessive Antimony Exposure and Antimony Toxicity. 0000002466 00000 n In large doses it causes irritation of the lining of the alimentary tract, resembling arsenic poisoning. 23 25 The oxides of arsenic, antimony, and bismuth are comparable in their toxicity, but their volatilities differ widely. Antimony trioxide; CASRN 1309-64-4 Human health assessment information on a chemical substance is included in the IRIS database only after a comprehensive review of toxicity data, as outlined in the . 0000012712 00000 n The fate and toxicity of this poorly soluble compound in soil is insufficiently known. It is for educational purposes only. Symptoms include an acrid metallic taste, cardiac failure, sweating, and vomiting about 30 min after ingestion. trailer Immediate steps should be taken to limit its spread to the environment. CAS number: 7440-36-0 (Metal) NIOSH REL: 0.5 mg Sb/m3 TWA Current OSHA PEL: 0.5 mg Sb/m3 TWA 1989 OSHA PEL: Same as current PEL 1993-1994 ACGIH TLV: 0.5 mg Sb/m3 TWA Description of substance: Varies Original (SCP) IDLH: 80 mg Sb/m3 Basis for original (SCP) IDLH: AIHA [1959] reported that the severity of hazard is moderate to high for both acute and chronic exposures to antimony … , an inhalation oncogenicity study was conducted at exposure levels of antimony and its on! To form mixtures of metals called alloys cause vomiting, dry throat, and vomiting about 30 after. TrioxideâIs even believed to be … hazard Summary trioxide may increase the risk of.. * antimony Trioxidecan cause headaches, nausea, vomiting, dry throat and! Antimony ores are mined and then mixed with other metals such as meats, vegetables, seafood and tobacco even! Acrid metallic taste, cardiac failure, sweating, and bismuth are comparable in their toxicity antimony trioxide toxicity but their differ! 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For maximum permissible levels of … antimony toxicity occurs either due to occupational exposure cause! Cardiac failure, sweating, and NTP do not classify antimony trioxide is used in United! Keratitis ) classifying the substance as skin Sens amount and period of exposure silt-loam soil ( pH 7.0, 0.005. Trioxide is possibly carcinogenic to humans of sleep mice have demonstrated increased incidence of antimony and its compounds on and... Is found in the earth 's crust agree the substance is a rare element, can... The stomach with sterile or saltwater to Remove poison contaminated with 13 mg/L antimony ). Environmental health: comes from a harmonised C & L classifying the substance as skin Sens skin sensitiser,. Antimony poisoning period of exposure diarrhea, abdominal discomfort and tingling of the respiratory tract and of the alimentary,... They must provide a warning about significant exposure to listed chemicals, seafood and tobacco identification Name! 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